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2025-05-17 08:40:55
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title
Journal Article Reading (B)Log
description
image
site name
author
updated
2026-02-24 23:41:07
raw text
Journal Article Reading (B)Log Journal Article Reading (B)Log Thursday, May 24, 2007 A Pd(0)-Catalyzed Diamination of Terminal Olefins at Allylic and Homoallylic Carbons via Formal C-H Activation under Solvent-Free Conditions Link: JACS ASAP Haifeng Du, Weicheng Yuan, Baoguo Zhao, and Yian Shi* Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523 This is a new method di-amidation of terminal alkenes at the allylic and homoallylic positions using di-tert-butyldiaziridinone ( 2 ). A similar method was reported before with conjugated diene 1 . In this method, terminal alkene 4 was used to give similar product. The reaction is applicable to a variety of alkenes, affording products with trans -stereochemistry in modest to excellent yields. The products of the current reaction is useful in further transforming to give 1,2-diamines such as 6 . In addition to mono alkenes, the reaction was also applied to bis-terminal alkenes. In case of ...
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